Chirality effects on core-periphery connection in a star-burst type tetranuclear Ru(III) complex: application of vibrational circular dichroism spectroscopy.
نویسندگان
چکیده
Vibrational circular dichroism (VCD) spectroscopy was applied to study the stereochemical properties of a star-burst type tetranuclear Ru(III) complex, Δ-(or Λ-)[{Δ-(or Λ-)-Ru(III)(acac)(2)(taet)}(3)Ru(III)] (acac = acetylacetonato; taet = tetraacetylethanato). By comparing the VCD spectra of eight diastereomeric enantiomers, it was shown that the spectra reflected the homo- or hetero-chiral nature of the bridging part connecting the central core and the peripheral region.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 6 شماره
صفحات -
تاریخ انتشار 2012